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Piano grass (Themeda arguens), reputed to have been introduced to Jamaica as packing material in an imported piano1 . There are about 27 varieties of this highly invasive grass/weed worldwide[1] and in Jamaica the species previously identified as Themeda arguens is of concern as it has progressively taken over lawns, pastures and roadsides [1]. The grass is of particular concern to livestock farmers due to its highly invasive and aggressive nature and the concomitant negative effect on livestock productivity, especially during its annual seeding period (November/December – April) [2], when the palatability of the grass diminishes significantly and the seed awns can cause severe damage to the mouth when consumed, and feet of livestock [2], sometimes requiring veterinary intervention.
Pesticide usage in agriculture has occurred for centuries and led to significant positive outcomes in food production and noticeable reduction in crop losses. However, pesticide usage on food crops often results in the presence of toxic pesticide residues on food produce, which is the main route of exposure to pesticides in humans. The toxicity of the pesticide residues can potentially cause debilitating effects to major human organs and body systems. Pesticide residue analysis addresses the issue of pesticide residues in foods by screening and quantifying the levels of pesticides in food commodities.
Benzylideneanilines, the condensation products of benzaldehyde and aniline derivatives, have enjoyed significant success as optical metal ion sensors due to their ability to form stable metal complexes which exhibit distinct spectral features compared to the unbound compound. However, their use in aqueous media is limited by the hydrolytic susceptibility of the C=N moiety. Hence, an in-depth investigation into the hydrolytic degradation mechanism of a series of 2-aminophenol derived Nbenzylideneanilines was conducted wherein molecular modelling techniques were applied to elucidate the “step-by-step” transformation mechanism of these compounds from a fundamental perspective.
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