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Benzylideneanilines, the condensation products of benzaldehyde and aniline derivatives, have enjoyed significant success as optical metal ion sensors due to their ability to form stable metal complexes which exhibit distinct spectral features compared to the unbound compound. However, their use in aqueous media is limited by the hydrolytic susceptibility of the C=N moiety. Hence, an in-depth investigation into the hydrolytic degradation mechanism of a series of 2-aminophenol derived Nbenzylideneanilines was conducted wherein molecular modelling techniques were applied to elucidate the “step-by-step” transformation mechanism of these compounds from a fundamental perspective.
A major challenge facing farmers in Portland, Jamaica is dry weather, especially during the optimal growing season from April through August. During this five-month period Portland suffered from severe dry spells during the years 2014, 2015, 2018 and 2020. A second challenge is the damage to crops and land as well as loss of livestock due to tropical storms or hurricanes and the associated flooding. Portland farmers have suffered losses due to an active hurricane season numerous times and most recently in the years 2004, 2005, 2012 and 2020.
The burgeoning of small gourmet chocolate boutiques worldwide serves as a key driver for niche and ultra-niche marketing of cocoa (Theobroma cacao L.), branded as (a) geographical indication (b) estate origin or (c) based on unique genetics. Over 90% of the cacao farms globally, are small with an average size between 2 and 5 hectares and can benefit from supplying to the gourmet boutiques.
Oral malodour called halitosis, and commonly referred to as ‘bad breath’, is a socially offensive and discriminating occurrence that requires effective management for health improvement and avoidance of debasing stratification of sufferer. Halitosis has been reported to be prevalent in up to 50% of the general population in the USA, and about 6-23% in China. Between 80% and 85% of halitosis cases are caused by intraoral conditions. Literature on halitosis in Jamaica is either scarce or non-existent. Prior to the COVID-19 pandemic, a common malodour that seemed to be spreading among persons through oral interaction by face-to-face contact with a sufferer was observed among the general populace in Mandeville, Manchester, Jamaica.
Loan management is a complex process that coordinates agreements among multiple stakeholders in such a way that each party benefits from the arrangement [2]. At the core of our work there is the Asset Token (ATK) which is a compliant ERC-20 token and used for all financial transactions in our proposed system. With this token in our private blockchain network [1], stakeholders can interact in a digital market. Our work includes a Non-Fungible Vehicle Token (VTK) and represents the physical vehicle. Users has access to the ownership of this NFT which prevents fraudulent transactions.
Pesticide usage in agriculture has occurred for centuries and led to significant positive outcomes in food production and noticeable reduction in crop losses. However, pesticide usage on food crops often results in the presence of toxic pesticide residues on food produce, which is the main route of exposure to pesticides in humans. The toxicity of the pesticide residues can potentially cause debilitating effects to major human organs and body systems. Pesticide residue analysis addresses the issue of pesticide residues in foods by screening and quantifying the levels of pesticides in food commodities.
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